Research Article: Bromido({2-[2-(diphenyl­phosphan­yl)benzyl­idene]hydrazin-1-yl­idene}(4-meth­oxy­anilino)methane­thiol­ato)palladium(II) acetone monosolvate

Date Published: July 01, 2012

Publisher: International Union of Crystallography

Author(s): Khalisah Asilah Mokthar, Mustaffa Shamsuddin, Mohd Mustaqim Rosli, Hoong-Kun Fun.


In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intra­molecular C—H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol­ecules form infinite chains along the a-axis direction through C—H⋯Br inter­actions, and a C—H⋯O inter­action links the main mol­ecule with the acetone solvent mol­ecule.

Partial Text

For the properties of palladium(II)–imino­phosphine complexes, see: Mahamo et al. (2012 ▶); Nobre & Monteiro (2009 ▶); Scrivanti et al. (2009 ▶); Sánchez et al. (2010 ▶); Mogorosi et al. (2011 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶).




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