Date Published: July 01, 2012
Publisher: International Union of Crystallography
Author(s): Jun Ji, Yuan-Fa Yang, Yi-Hang Wen.
The title compound, [Mn(C11H8O5)(C12H8N2)(H2O)2]·H2O, was obtained under hydrothermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN2O4 octahedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxylate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in . Intermolecular O—H⋯O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water molecules are present.
For the study of metal-organic frameworks, see: Zhang et al. (2008 ▶); Zheng et al. (2010 ▶); Wang et al. (2006 ▶); Yi et al. (2005 ▶). For related structures, including 1,10-phenanthroline as a ligand, see: Chen et al. (2005 ▶); Ma et al. (2005 ▶); For the coordination modes of carboxymethoxy acids, see: Novitchi et al. (2005 ▶).