Research Article: catena-Poly[[[diaqua­(1,10-phenan­thro­line)manganese]-μ-3-[3-(carboxyl­ato­meth­oxy)phen­yl]acrylato] monohydrate]

Date Published: July 01, 2012

Publisher: International Union of Crystallography

Author(s): Jun Ji, Yuan-Fa Yang, Yi-Hang Wen.


The title compound, [Mn(C11H8O5)(C12H8N2)(H2O)2]·H2O, was obtained under hydro­thermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN2O4 octa­hedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxyl­ate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Inter­molecular O—H⋯O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water mol­ecules are present.

Partial Text

For the study of metal-organic frameworks, see: Zhang et al. (2008 ▶); Zheng et al. (2010 ▶); Wang et al. (2006 ▶); Yi et al. (2005 ▶). For related structures, including 1,10-phenanthroline as a ligand, see: Chen et al. (2005 ▶); Ma et al. (2005 ▶); For the coord­ination modes of carb­oxy­meth­oxy acids, see: Novitchi et al. (2005 ▶).




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