Research Article: Chloridobis(2-chloro­benz­yl)(quinolin-8-olato-κ2N,O)tin(IV)

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Thy Chun Keng, Kong Mun Lo, Seik Weng Ng.

http://doi.org/10.1107/S160053681101573X

Abstract

The SnIV atom in the three independent mol­ecules of the title compound, [Sn(C7H6Cl)2(C9H6NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C2SnNOCl trigonal–bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.

Partial Text

For the direct synthesis of the organotin chloride reactant, see: Sisido et al. (1961 ▶). For related structures, see: Shi & Hu (1987 ▶); Vafaee et al. (2010 ▶).

Source:

http://doi.org/10.1107/S160053681101573X