Date Published: June 01, 2011
Publisher: International Union of Crystallography
Author(s): Thy Chun Keng, Kong Mun Lo, Seik Weng Ng.
The SnIV atom in the three independent molecules of the title compound, [Sn(C7H6Cl)2(C9H6NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C2SnNOCl trigonal–bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.
For the direct synthesis of the organotin chloride reactant, see: Sisido et al. (1961 ▶). For related structures, see: Shi & Hu (1987 ▶); Vafaee et al. (2010 ▶).