Research Article: Chlorido{N-[2-(diphenylphosphanyl)benz­ylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): Martin O. Onani, William M. Motswainyana, Emmanuel I. Iwuoha, James Darkwa, Roger A. Lalancette.


In the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio­phene ring is equally disordered over two orientations and the dichloro­methane solvent mol­ecule is disordered about an inversion centre.

Partial Text

For metal-organic compounds with ligands containing both pyridyl and phosphine donor groups and for typical Pd—C, Pd—Cl, Pd—P and Pd—N bond lengths, see: Shaffer & Schmidt (2009 ▶). For the properties of related compounds, see: Tongwa et al. (2009 ▶); Jun-Gill et al. (2009 ▶).




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