Research Article: Chlorido(pentane-2,4-dionato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II)

Date Published: August 01, 2009

Publisher: International Union of Crystallography

Author(s): Yew Sent Wong, Chew Hee Ng, Seik Weng Ng.

http://doi.org/10.1107/S1600536809027111

Abstract

The CuII atom in the title compound, [Cu(C5H7O2)Cl(C12H8N2)], shows a distorted square-planar coordination; the chelating N and O atoms occupy the basal sites and the Cl atom the apical site. The square-pyramidal character along the Berry D3h–C4v pseudorotation pathway is 92%.

Partial Text

For the synthesis and electronic spectrum, see: Kwik & Ang (1978 ▶). For isostructural CuBr(C12H8N2)(C5H7O2), see: Onawumi et al. (2008 ▶).

 

Source:

http://doi.org/10.1107/S1600536809027111

 

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