Research Article: (Cinnamato-κ2O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate

Date Published: August 01, 2012

Publisher: International Union of Crystallography

Author(s): Qiang Gao, Yi-Cheng Cao.

http://doi.org/10.1107/S1600536812032175

Abstract

In the title compound, [Ni(C9H7O2)(C16H36N4)]ClO4·H2O, the macrocyclic 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane ligand (L) folds around the NiII atom, which is also chelated by the carboxyl­ate group. The geometry is a distorted N4O2 octa­hedron. In the crystal, adjacent mol­ecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into a zigzag chain parallel to [010].

Partial Text

For background to this study, see: Tait & Busch (1976 ▶); Curtis (1965 ▶). For related structures, see: Ou et al. (2008 ▶, 2009a ▶,b ▶); Ou & Ng 2010a ▶,b ▶).

Source:

http://doi.org/10.1107/S1600536812032175