Research Article: Di-μ-aqua-bis­{diaqua­[μ-4-({4-[bis­(2-hy­droxy­eth­yl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)­benzene­sulfonato]­sodium(I)}

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Mei Zhang, Fu-Yu Sun, Gui-Zhe Zhao, Ya-Qing Liu.


In the dinuclear title compound, [Na2(C13H15ClN5O5S)2(H2O)6]n, two Na+ cations, disposed about a centre of inversion, are linked by two bridging water mol­ecules. The coordination geometry is based on an O5 donor set defined by four water mol­ecules and a 4-amino­benzene­sulfonate O atom in a distorted trigonal–bipyramidal geometry. In the crystal, significant O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds lead to the formation of a three-dimensional architecture.

Partial Text

For commercial and synthetic applications of related compounds, see: Candiani & Frigerio (2007 ▶); Hollink et al. (2005 ▶); Konstantion & Petrova (2002 ▶).




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