Research Article: Dibenzyl­dichloridotin(IV)

Date Published: May 01, 2009

Publisher: International Union of Crystallography

Author(s): Kong Mun Lo, Seik Weng Ng.

http://doi.org/10.1107/S160053680901513X

Abstract

The title compound, [Sn(C7H7)2Cl2], exists as a monomeric tetra­hedral mol­ecule. The Sn atom lies on a special position of site symmetry 2. Adjacent mol­ecules are linked into a linear chain running along the b axis of the monoclinic unit cell by Sn⋯Cl bridges of 3.7275 (4) Å.

Partial Text

For the synthesis of dibenzyl­tin dichloride by the direct reaction of benzyl chloride and metallic tin, see: Shishido et al. (1961 ▶). For an overview of crystallographic and theoretical structures of diorganotin dichlorides, see: Buntine et al. (2003 ▶).

 

Source:

http://doi.org/10.1107/S160053680901513X

 

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