Research Article: Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl­ate-κN)zinc

Date Published: March 01, 2012

Publisher: International Union of Crystallography

Author(s): Can Li, Guilong Zhang, Zhenming Yin.

http://doi.org/10.1107/S1600536812001353

Abstract

In the title mol­ecule, [ZnCl2(C11H10N2O2)2], the ZnII ion, situated on a twofold axis, is in a distorted tetra­hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl­ate unit, the pyrrole N—H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol­ecules are connected into chains extending along [101] by N—H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C—H⋯O and C—H⋯Cl inter­actions.

Partial Text

For the hydrogen-bonded assemblies of pyrrole-based structures, see: Wang & Yin (2007 ▶); Yin & Li (2006 ▶); Cui et al. (2009 ▶).

 

Source:

http://doi.org/10.1107/S1600536812001353