Research Article: (Ethano­lato-κO)[N′-(3-meth­oxy-2-oxidobenzyl­idene-κO2)benzo­hydrazidato-κ2N′,O]oxidovanadium(V)

Date Published: August 01, 2012

Publisher: International Union of Crystallography

Author(s): Xiao-Hua Chen, Qiong-Jie Wu, Li-Juan Chen, Ming-Xing Yang.


In the title complex, [V(C15H12N2O4)(C2H5O)O], the VV ion is coordinated by an oxide O atom, an ethano­late anion and two O atoms and one N atom from the tridentate benzo­hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intra­molecular O—H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal.

Partial Text

For general background to the coordination chemistry and biochemisty of vanadium, see: Deng et al. (2007 ▶); Monfared et al. (2011 ▶); Sutradhar et al. (2006 ▶). For related structures, see: Chen et al. (2004 ▶); Liu et al. (2006 ▶); Ghosh et al. (2007 ▶); Seena et al. (2008 ▶). For the synthesis, see: Gao et al. (1998 ▶); Huang et al. (2010 ▶).




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