Research Article: Ethyl 2-[4-(2-chloro­benzo­yl)-2,6-di­methyl­phen­oxy]ethano­ate

Date Published: August 01, 2012

Publisher: International Union of Crystallography

Author(s): T. Prashanth, V. Lakshmi Ranganatha, M. K. Usha, Shaukath Ara Khanum, D. Revannasiddaiah, Sumati Anthal, Rajni Kant, Vivek K. Gupta.

http://doi.org/10.1107/S1600536812030693

Abstract

The asymmetric unit of the title compound, C19H19ClO4, contains two independent mol­ecules. The dihedral angles between the benzene rings are 63.41 (8) and 61.41 (9)°. Adjacent mol­ecules of different types are inter­connected in pairs through π–π inter­actions between their central benzene rings [centroid–centroid separation = 3.801 (2) Å, inter­planar spacing = 3.605 (2) Å, centroid shift = 1.204 (2) Å]. Finally, C—H⋯O hydrogen bonds link these dimers into bilayers parallel to (100).

Partial Text

For general background to phen­oxy­ethanoic acid, see: Dahiya & Kaur (2007 ▶); Esbenshade et al. (1990 ▶). For biological activity, see: Prabhakar et al. (2006 ▶); Sudha et al. (2003 ▶); Ma et al. (2011 ▶); Khanum et al. (2010 ▶). For bond-length data, see: Allen et al. (1987 ▶).

 

Source:

http://doi.org/10.1107/S1600536812030693

 

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