Date Published: May 01, 2009
Publisher: International Union of Crystallography
Author(s): J. Y. Gao, Z. Liu, Y. Wang.
In the title compound, [Ni(C8H5Cl2N3OS)(C12H8N2)(CH3OH)], the NiII atom is octahedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thiosemicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N—H⋯Cl, N—H⋯N, C—H⋯S and O—H⋯S hydrogen bonds.
For nickel complexes with salicylic aldehyde thiosemicarbazone ligands, see: Dapporto et al. (1984 ▶); Schulte et al. (1991 ▶); García-Reynaldos et al. (2007 ▶); Kolotilov et al. (2007 ▶); Qiu & Wu (2004 ▶). For related Cu(II) compounds with a distorted octahedral coordination as a result of the Jahn–Teller effect, see: García-Orozco et al. (2002 ▶). For bond-length data, see: Orpen et al. (1989 ▶). For related structures, see: Seena & Kurup (2007 ▶); Wang et al. (2008 ▶); Zhang et al. (2007 ▶).