Research Article: Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Azhar Ariffin, Nordiana Nordin, Wagee A. Yehye, Seik Weng Ng.

http://doi.org/10.1107/S1600536812018739

Abstract

The title solvated ester, C22H29NO3S·0.5C6H14, crystallizes with two independent mol­ecules along with a hexane mol­ecule in the asymmetric unit. The two aromatic rings are separated by an –CH2–S– linkage; the rings are aligned at 83.27 (4)° in one mol­ecule and 47.66 (7)° in the other. The hy­droxy group of one mol­ecule forms an O—H⋯O hydrogen bond to the other mol­ecule.

Partial Text

For the synthesis of carb­oxy­lic acid, see: Mansor et al. (2008 ▶).

 

Source:

http://doi.org/10.1107/S1600536812018739

 

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