Date Published: April 01, 2011
Publisher: International Union of Crystallography
Author(s): Ibrahim N. Hassan, Chong Yan Yi, Mohammad B. Kassim.
In the title compound, C12H14N2O3S, the propyl acetate group and the benzoyl group adopt a cis–trans conformation, respectively, with respect to the thiono S atom across the C—N bonds. The phenyl ring is twisted relative to the the thiourea mean plane, forming a dihedral angle of 24.16 (9)°. An intramolecular N—H⋯O hydrogen bond occurs. The crystal packing is stabilized by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming a chain along the a axis.
For bond-length data, see: Allen et al. (1987 ▶). For related strutures, see: Yamin & Hassan (2004 ▶); Hassan et al. (2008a ▶,b ▶,c ▶, 2009 ▶), Hung et al. (2010 ▶). For a related synthesis, see: Hassan et al. (2008a ▶).