Research Article: Methyl 3-(3-benzoyl­thio­ureido)propano­ate

Date Published: April 01, 2011

Publisher: International Union of Crystallography

Author(s): Ibrahim N. Hassan, Chong Yan Yi, Mohammad B. Kassim.


In the title compound, C12H14N2O3S, the propyl acetate group and the benzoyl group adopt a cis–trans conformation, respectively, with respect to the thiono S atom across the C—N bonds. The phenyl ring is twisted relative to the the thio­urea mean plane, forming a dihedral angle of 24.16 (9)°. An intra­molecular N—H⋯O hydrogen bond occurs. The crystal packing is stabilized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, forming a chain along the a axis.

Partial Text

For bond-length data, see: Allen et al. (1987 ▶). For related strutures, see: Yamin & Hassan (2004 ▶); Hassan et al. (2008a ▶,b ▶,c ▶, 2009 ▶), Hung et al. (2010 ▶). For a related synthesis, see: Hassan et al. (2008a ▶).




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