Research Article: N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate

Date Published: May 01, 2012

Publisher: International Union of Crystallography

Author(s): Qian-Shou Zong.


In the title compound, C15H13FN2O3·CH3OH, the dihedral angle between the benzene rings of the benzohydrazone mol­ecule is 5.3 (3)°. The C atom of the meth­oxy group is almost coplanar with its attached ring [deviation = 0.017 (2) Å]. The r.m.s. deviation of the 21 non-H atoms of the hydrazone mol­ecule is 0.106 Å. In the crystal, the components are linked by Om—H⋯Oh, Nh—H⋯Om and Oh—H⋯Oh (m = methanol and h = hydrazone) hydrogen bonds, forming (001) layers.

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For related structures, see: Horkaew et al. (2012) ▶; Fun et al. (2011 ▶); Zhang (2011 ▶).