Research Article: N′-(3-Hy­droxy­benzyl­idene)-4-methyl­benzohydrazide

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Ji-Lai Liu, Ming-Hui Sun, Jing-Jun Ma.


The title compound, C15H14N2O2, was obtained from the reaction of 3-hy­droxy­benzaldhyde and 4-methyl­benzo­hydrazide in methanol. In the mol­ecule, the benzene rings form a dihedral angle of 2.9 (3)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to (101). The crystal packing also exhibits π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.686 (4) Å].

Partial Text

For the biological activity of benzohydrazide compounds, see: El-Sayed et al. (2011 ▶); Horiuchi et al. (2009 ▶). For benzohydrazide coordination compounds, see: El-Dissouky et al. (2010 ▶); Zhang et al. (2010 ▶). For standard bond lengths, see: Allen et al. (1987 ▶). For the crystal structures of similar compounds, see: Suleiman Gwaram et al. (2010 ▶); Liu et al. (2011 ▶); Zhang et al. (2012 ▶).




0 0 vote
Article Rating
Notify of
Inline Feedbacks
View all comments