Research Article: [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-3-hydr­oxy-2-naphthohydrazidato-κ2N′,O]dibutyl­tin(IV)

Date Published: August 01, 2009

Publisher: International Union of Crystallography

Author(s): See Mun Lee, Kong Mun Lo, Hapipah Mohd Ali, Seik Weng Ng.

http://doi.org/10.1107/S1600536809024477

Abstract

The SnIV atom in the title compound, [Sn(C4H9)2(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60 (1):0.40 (1) ratio.

Partial Text

The dianions of similar N′-(2-hydroxy­benzyl­idene)benzohydrazones O,N,O′-chelate to tin in organotin compounds; see: Labib et al. (1996 ▶); Samanta et al. (2007 ▶).

Source:

http://doi.org/10.1107/S1600536809024477