Research Article: N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): B. Thimme Gowda, Sabine Foro, P. G. Nirmala, Hartmut Fuess.


In the title compound, C14H14ClNO2S, the conformation of the N—C bond in the C—SO2—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO2—NH—C torsion angle of −54.9 (2)°. The sulfonyl and aniline benzene rings are rotated relative to each other by 75.7 (1)°. An intra­molecular N—H⋯Cl hydrogen bond is present. In the crystal, inter­molecular N—H⋯O hydrogen-bonding inter­actions are observed and the mol­ecules are packed into chains parallel to the b axis.

Partial Text

For the preparation of the title compound, see: Savitha & Gowda (2006 ▶). For related structures, see: Gelbrich et al. (2007 ▶); Gowda et al. (2009a ▶,b ▶, 2010 ▶); Nirmala et al. (2009 ▶); Perlovich et al. (2006 ▶).




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