Research Article: N-(2-Chloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): B. Thimme Gowda, Sabine Foro, P. G. Nirmala, Hartmut Fuess.

http://doi.org/10.1107/S1600536810015916

Abstract

In the title compound, C14H14ClNO2S, the conformation of the N—C bond in the C—SO2—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the S atom with a C—SO2—NH—C torsion angle of −54.9 (2)°. The sulfonyl and aniline benzene rings are rotated relative to each other by 75.7 (1)°. An intra­molecular N—H⋯Cl hydrogen bond is present. In the crystal, inter­molecular N—H⋯O hydrogen-bonding inter­actions are observed and the mol­ecules are packed into chains parallel to the b axis.

Partial Text

For the preparation of the title compound, see: Savitha & Gowda (2006 ▶). For related structures, see: Gelbrich et al. (2007 ▶); Gowda et al. (2009a ▶,b ▶, 2010 ▶); Nirmala et al. (2009 ▶); Perlovich et al. (2006 ▶).

 

Source:

http://doi.org/10.1107/S1600536810015916

 

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