Date Published: July 01, 2012
Publisher: International Union of Crystallography
Author(s): Alaa A.-M. Abdel-Aziz, Adel S. El-Azab, Magda A. El-Sherbeny, Seik Weng Ng, Edward R. T. Tiekink.
In the title compound, C14H20N2O2S, the sulfonamide O atoms lie to one side of the benzene ring and the aminobicycloheptanyl to the other side [Car—S—N—C torsion angle = −57.93 (11)°; ar = aromatic]. An intramolecular N—H⋯N hydrogen bond is formed. In the crystal, a supramolecular chain is formed along the b axis via N—H⋯O and N—H⋯N hydrogen bonds.
For chiral ligands in asymmetric catalytic reactions, see: Seo et al. (2001 ▶); Abdel-Aziz et al. (2004 ▶); Matsunaga et al. (2005 ▶); Yamakuchi et al. (2005 ▶).