Research Article: N-(3-Amino­bicyclo­[2.2.1]heptan-2-yl)-4-methyl­benzene­sulfonamide

Date Published: July 01, 2012

Publisher: International Union of Crystallography

Author(s): Alaa A.-M. Abdel-Aziz, Adel S. El-Azab, Magda A. El-Sherbeny, Seik Weng Ng, Edward R. T. Tiekink.


In the title compound, C14H20N2O2S, the sulfonamide O atoms lie to one side of the benzene ring and the amino­bicyclo­hepta­nyl to the other side [Car—S—N—C torsion angle = −57.93 (11)°; ar = aromatic]. An intra­molecular N—H⋯N hydrogen bond is formed. In the crystal, a supra­molecular chain is formed along the b axis via N—H⋯O and N—H⋯N hydrogen bonds.

Partial Text

For chiral ligands in asymmetric catalytic reactions, see: Seo et al. (2001 ▶); Abdel-Aziz et al. (2004 ▶); Matsunaga et al. (2005 ▶); Yamakuchi et al. (2005 ▶).




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