Research Article: N-(3,5-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide

Date Published: May 01, 2010

Publisher: International Union of Crystallography

Author(s): P. G. Nirmala, B. Thimme Gowda, Sabine Foro, Hartmut Fuess.

http://doi.org/10.1107/S1600536810013504

Abstract

In the crystal structure of the title compound, C14H13Cl2NO2S, the conformation of the N—C bond in the C—SO2—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is bent at the N atom, with an C—SO2—NH—C torsion angle of −54.9 (3)°. The two benzene rings are tilted relative to each other by 82.3 (2)°. The mol­ecules are linked into centrosymmetric R22(8) motifs by N—H⋯O hydrogen bonds and C—H⋯π inter­actions along [100].

Partial Text

For the preparation of the compound, see: Savitha & Gowda (2006 ▶). For our study of the effect of substituents on the structures of N-(ar­yl)aryl­sulfonamides, see: Gowda et al. (2008 ▶, 2009a ▶,b ▶). For related structures, see: Gelbrich et al. (2007 ▶); Perlovich et al. (2006 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶).

 

Source:

http://doi.org/10.1107/S1600536810013504

 

0 0 vote
Article Rating
Subscribe
Notify of
guest
0 Comments
Inline Feedbacks
View all comments