Research Article: Oxalic acid–pyridine-4-carbonitrile (1/2)

Date Published: June 01, 2012

Publisher: International Union of Crystallography

Author(s): Wen-Ni Zheng.

http://doi.org/10.1107/S1600536812019137

Abstract

In the title compound, 2C6H4N2·C2H2O4, the oxalic acid mol­ecule lies about an inversion center. The pyridine ring of the pyridine-4-carbonitrile mol­ecule is almost planar, the largest deviation from the least-squares plane being 0.006 (1) Å; the nitrile N atom deviates from this plane by 0.114 (1) Å. In the crystal, the oxalic acid mol­ecules and the pyridine-4-carbonitrile mol­ecules form stacks. Neighboring mol­ecules within the stacks are related by translation in the a direction, with inter­planar distances of 3.183 (1) and 3.331 (2) Å, respectively. Each oxalic acid mol­ecule forms strong O—H⋯N hydrogen bonds with two mol­ecules of pyridine-4-carbonitrile. Besides this, there are also weak C—H⋯O inter­actions.

Partial Text

For the structures and ferroelectric properties of related compounds, see: Fu et al. (2011a ▶,b ▶,c ▶); Dai & Chen (2011 ▶); Xu et al. (2011 ▶); Zheng (2011 ▶). For standard bond lengths, see: Allen et al. (1987 ▶).

 

Source:

http://doi.org/10.1107/S1600536812019137

 

0 0 vote
Article Rating
Subscribe
Notify of
guest
0 Comments
Inline Feedbacks
View all comments