Research Article: Poly[1,4-bis­(ammonio­meth­yl)cyclo­hexane [di-μ-chlorido-dichloridoplumbate(II)]]

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): Matthew Kyle Rayner, David Gordon Billing.

http://doi.org/10.1107/S1600536810016818

Abstract

The title compound, {(C8H20N2)[PbCl4]}n, crystallizes as an layered inorganic–organic hybrid perovskite-type structure. Corner-sharing PbCl6 octa­hedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit symmetry and inter­act with the inorganic sheets via N—H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.

Partial Text

Similar structures have been reported by Billing & Lemmerer (2006 ▶) and Dobrzycki & Woźniak (2009 ▶). Structure–properties relation experiments have been performed by Mitzi et al. (2001 ▶). For hydrogen-bonding nomenclature for inorganic–organic hybrids, see: Mitzi (1999 ▶). For the bromido- and iodidoplumbate(II) analogues of the title compound, see: Rayner & Billing (2010a ▶,b ▶).

Source:

http://doi.org/10.1107/S1600536810016818