Research Article: Poly[bis­(μ2-pyrimidine-κ2N:N′)bis­(seleno­cyanato-κN)zinc]

Date Published: July 01, 2011

Publisher: International Union of Crystallography

Author(s): Jan Boeckmann, Thorben Reinert, Christian Näther.


The asymmetric unit of the title compound, [Zn(NCSe)2(C4H4N2)2]n, consists of one Zn2+ cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded seleno­cyanate anions in mutually trans orientations within a slightly distorted octa­hedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).

Partial Text

For isotypic structures with different divalent transition metals and thio­cyanate ligands, see: Bhosekar et al. (2010 ▶); Lloret et al. (1998 ▶, 1999 ▶); Wriedt et al. (2009 ▶); Wriedt & Näther (2010 ▶).




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