Date Published: May 01, 2012
Publisher: International Union of Crystallography
Author(s): Jian-Guo Wang, Yuan Zhang, Zhong-Xing Su, Xiang Liu.
In the title compound, [Cd(NCS)2(C4H6N4O2)2]n, the CdII cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN− anions and two N atoms from two 3-(1H-tetrazol-1-yl)propanoic acid (Htzp) ligands in a distorted octahedral geometry. The SCN− anions bridge the CdII cations into a layer structure parallel to (100). A weak intramolecular C—H⋯N interaction occurs. The layers are further assembled into a three-dimensional supramolecular structure via classical O—H⋯O hydrogen bonds.
For general background to carboxylate-tetrazole complexes, see: Yang et al. (2009 ▶); He et al. (2005 ▶); Yu et al. (2008 ▶); Dong et al. (2008 ▶); Zhang et al. (2009 ▶); Li et al. (2008 ▶, 2010 ▶); Xie et al. (2010 ▶); Bai et al. (2008 ▶); Voitekhovich et al. (2010 ▶).