Research Article: Poly[diethyl­enetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]

Date Published: June 01, 2010

Publisher: International Union of Crystallography

Author(s): Xiu-Mei Zhang, Ya-Feng Li.

http://doi.org/10.1107/S1600536810016600

Abstract

A new organically templated open-framework cerium sulfate, {(C4H16N3)[Ce(SO4)3(H2O)]}n, was hydro­thermally synthesized. The CeIII cation is nine-coordinated by nine O atoms, including one water mol­ecule. Two of the SO4 groups afford one monodentate and bidentate linkages as the bridge to connect adjacent CeIII cations, while the third SO4 group attaches the CeIII cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring networks formed by four CeO9 polyhedra and four SO4 tetra­hedra. The triply protonated diethyl­enetriamine cations are located between adjacent layers and connect the layers via hydrogen bonds.

Partial Text

For related literature, see: Choudhury et al. (2001 ▶); Fu et al. (2006 ▶); Paul et al. (2002 ▶); Rao et al. (2006 ▶); Wickleder (2002 ▶).

 

Source:

http://doi.org/10.1107/S1600536810016600

 

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