Research Article: (S)-2-[(2-Hy­droxy­benz­yl)aza­nium­yl]-4-(methyl­sulfan­yl)butano­ate

Date Published: June 01, 2011

Publisher: International Union of Crystallography

Author(s): Giovanna Brancatelli, Giuseppe Bruno, Francesco Nicoló, Loredana Canfora, Giuseppe Ruisi.

http://doi.org/10.1107/S1600536811016564

Abstract

The zwitterionic title compound, C12H17NO3S, is a reduced Schiff base derived from (S)-N-(2-hy­droxy­benzyl­idene)methio­nine. An intra­molecular inter­action between the N—H and carboxyl­ate groups forms a roughly planar (r.m.s. deviation = 0.1405 Å) five-membered ring containing the H(N), N, Cα, C(carboxyl­ate) and O atoms in a penta­gonal conformation. In the crystal, a supra­molecular triangle-shaped motif is generated by mol­ecules held together by O—H⋯O and N—H⋯O hydrogen bonds.

Partial Text

For transition metal complexes containing N-(2-hy­droxy­benz­yl)-α-amino acids as ligands, see: Bandyopadhyay et al. (2006 ▶); Beltrán et al. (2002 ▶); Ganguly et al. (2008 ▶); Koh et al. (1996 ▶); Martell (1989 ▶); Maurya (2003 ▶); Nefkens & Zwanenburg (1985 ▶); Ritsma (1975 ▶); Shongwe et al. (1999 ▶); Sreenivasulu & Vittal (2004 ▶); Wilson (1990 ▶).

 

Source:

http://doi.org/10.1107/S1600536811016564

 

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