Date Published: April 01, 2012
Publisher: International Union of Crystallography
Author(s): Victor A. Trush, Kateryna E. Gubina, Yaroslav O. Gumeniuk, Tetyana Yu. Sliva, Irina S. Konovalova.
The molecule of the title compound, C9H14F6N2O8P2, lies on a twofold rotation axis that passes through the middle C atom of the three-atom fluoromethylene unit. The carbonyl and phosphoryl groups are in an antiperiplanar conformation. In the crystal, N—H⋯O=P hydrogen bonds link the molecules into polymeric chains parallel to the c axis.
For background to the chemistry of phosphorus–organic compounds, see: Ly & Woollins (1998 ▶). For the biological and pharmacological properties of carbacylamidophosphate derivatives, see: Adams et al. (2002 ▶). For details of the synthesis and properties of phosphoramide derivatives, see: Kirsanov & Levchenko (1957 ▶); For structural analogues of phosphorylated carbacylamides and their properties, see: Trush et al. (2005 ▶); Gubina et al. (2000 ▶). For the synthesis and properties of fluorinated compounds, see: Leontieva et al. (2002 ▶).