Research Article: trans-Dichloridobis[diphen­yl(thio­phen-2-yl)phosphane-κP]palladium(II)

Date Published: May 01, 2012

Publisher: International Union of Crystallography

Author(s): Andrew R. Burgoyne, Reinout Meijboom, Haleden Chiririwa, Leo Kirsten.

http://doi.org/10.1107/S160053681201478X

Abstract

The title compound, trans-[PdCl2(C16H13PS)2], forms a monomeric complex with a trans-square-planar geometry. The Pd—P bond lengths are 2.3387 (11) Å, as the Pd atom lies on an inversion point, while the Pd—Cl bond lengths are 2.2950 (12) Å.

Partial Text

For a review on related compounds, see: Spessard & Miessler (1996 ▶). For the synthesis of the starting materials, see: Drew & Doyle (1990 ▶). For (R3P)2PdCl2 compounds with consanguinities, see: Muller & Meijboom (2010 ▶); Meijboom (2011 ▶); Burgoyne et al. (2012 ▶); Ogutu & Meijboom, (2011 ▶). For their applications, see: Bedford et al. (2004 ▶).

 

Source:

http://doi.org/10.1107/S160053681201478X