Research Article: trans-Tetra­kis(1-allyl-1H-imidazole-κN3)bis­(thio­cyanato-κN)nickel(II)

Date Published: February 01, 2012

Publisher: International Union of Crystallography

Author(s): Shao-Mei Zheng, Yan-Ling Jin.

http://doi.org/10.1107/S1600536812001584

Abstract

The structure of the title compound, [Ni(NCS)2(C6H8N2)4], consists of isolated mol­ecules of [Ni(NCS)2(Aim)4] (Aim = 1-allyl­imidazole), which contain a distorted octa­hedral NiN6 chromophore. The NCS− anions are trans and four N atoms from the 1-allyl­imidazole ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.105 (2) and 2.098 (2) Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability.

Partial Text

In the corresponding nickel compound [Ni(NCS)2(1-methyl­imidazole)4] (Liu et al., 2005 ▶), the NiII ions have a distorted octa­hedral environment.

 

Source:

http://doi.org/10.1107/S1600536812001584