Research Article: Tricarbonyl­chlorido(η5-cyclo­penta­dien­yl)molybdenum(II)

Date Published: April 01, 2012

Publisher: International Union of Crystallography

Author(s): Aloice O. Ogweno, Martin O. Onani.

http://doi.org/10.1107/S1600536812008471

Abstract

The structure of the title compound, [Mo(C5H5)Cl(CO)3], reveals a pseudo-square-pyramidal piano-stool coordination around the MoII ion, which is surrounded by a cyclo­penta­dienyl ring, three carbonyl groups and a chloride ligand.

Partial Text

For related structures, see: Chaiwasie & Fenn (1968 ▶); Churchill & Bueno (1981 ▶); Albright et al. (1978) ▶; Mays & Robb (1968 ▶). For applications of this class of compounds, see: Arzoumanian (1998 ▶); Freund et al. (2006 ▶); Karunadasa et al. (2010 ▶). For the synthesis, see: Amor et al. (2000 ▶); Atwood & Barbour (2003 ▶).

 

Source:

http://doi.org/10.1107/S1600536812008471