Research Article: Tricyclo­hex­yl(3,5-dibromo-2-hy­droxy­benzoato-κO)tin(IV)

Date Published: July 01, 2011

Publisher: International Union of Crystallography

Author(s): Xi-Cheng Liu, Wen-Tao Jiang, Peng-Cheng Shan, Wen-Chao Ding.


In the title compound, [Sn(C6H11)3(C7H3Br2O3)], the Sn atom is four-coordinate and possesses a distorted Sn(C3O) tetra­hedral geometry, with Sn—C bond lengths in the range 2.132 (6)–2.144 (6) Å and with Sn—O = 2.086 (4) Å. The uncoordinated carboxyl­ate O atom forms a weak contact with the Sn atom, with an Sn⋯O separation of 2.962 (2) Å.

Partial Text

For background information on organotin carboxyl­ate compounds, see: Davies et al. (2008 ▶); Tian et al. (2005 ▶). For related structures, see: Baul et al. (2001 ▶); Rauf et al. (2008 ▶); Smith et al. (1986 ▶); Song et al. (2002 ▶); Wang et al. (2007 ▶); Willem et al. (1998 ▶).




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