Use of Diffusion for Nuclear Energy Applications: Uranium Enrichment (OpenStax Chemistry 2e)
Gaseous diffusion has been used to produce enriched uranium for use in nuclear power plants and weapons. Naturally occurring uranium contains only 0.72% of 235U, the kind of uranium that is “fissile,” that is, capable of sustaining a nuclear fission chain reaction. Nuclear reactors require fuel that is 2–5% 235U, and nuclear bombs need even higher concentrations. One way to enrich uranium to the desired levels is to take advantage of Graham’s law. In a gaseous diffusion enrichment plant, uranium hexafluoride (UF6, the only uranium compound that is volatile enough to work) is slowly pumped through large cylindrical vessels called diffusers, which contain porous barriers with microscopic openings. The process is one of diffusion because the other side of the barrier is not evacuated. The 235UF6 molecules have a higher average speed and diffuse through the barrier a little faster than the heavier 238UF6 molecules. The gas that has passed through the barrier is slightly enriched in 235UF6 and the residual gas is slightly depleted. The small difference in molecular weights between 235UF6 and 238UF6 only about 0.4% enrichment, is achieved in one diffuser (Figure 1). But by connecting many diffusers in a sequence of stages (called a cascade), the desired level of enrichment can be attained.
The large scale separation of gaseous 235UF6 from 238UF6 was first done during the World War II, at the atomic energy installation in Oak Ridge, Tennessee, as part of the Manhattan Project (the development of the first atomic bomb). Although the theory is simple, this required surmounting many daunting technical challenges to make it work in practice. The barrier must have tiny, uniform holes (about 10–6 cm in diameter) and be porous enough to produce high flow rates. All materials (the barrier, tubing, surface coatings, lubricants, and gaskets) need to be able to contain, but not react with, the highly reactive and corrosive UF6.
Because gaseous diffusion plants require very large amounts of energy (to compress the gas to the high pressures required and drive it through the diffuser cascade, to remove the heat produced during compression, and so on), it is now being replaced by gas centrifuge technology, which requires far less energy. A current hot political issue is how to deny this technology to Iran, to prevent it from producing enough enriched uranium for them to use to make nuclear weapons.
Flowers, P., Theopold, K., Langley, R., & Robinson, W. R. (2019, February 14). Chemistry 2e. Houston, Texas: OpenStax. Access for free at: https://openstax.org/books/chemistry-2e
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